Increased dissolution of ilmenite induced by high-energy ball milling

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1999-11, Vol.271 (1), p.485-490
• Main Authors: Chen, Y., Williams, J.S., Campbell, S.J., Wang, G.M.
• Format: Article
• Language: English
• Subjects: Ball milling; Dissolution; Earth sciences; Earth, ocean, space; Exact sciences and technology; Ilmenite; Mineralogy; Non silicates
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/S0921-5093(99)00441-4

High-energy ball milling treatment leads to full dissolution of natural ilmenite sands containing both FeTiO 3 and Fe 2Ti 3O 9 phases in a sulphuric acid solution at 100°C. The ilmenite material has been milled for various times in two environments (vacuum and air), and characterised by X-ray diffraction, Mössbauer spectroscopy and surface area analysis. It is found that after milling for only 10 h, 50% of the sample can be dissolved as a result of the increased surface area, nanocrystalline structure and high level of lattice distortion present in the milled sample. Complete dissolution of the ilmenite is obtained on extended milling (200 h) in an oxygen free atmosphere. This occurs as a result of a gradual reduction of the Fe 3+ phase (Fe 2Ti 3O 9) to the relatively more soluble Fe 2+ phase (FeTiO 3) on milling in vacuum. The results overall show that the chemical reactivity of milled materials can be affected significantly by the milling conditions and environment.