A versatile route to planar chiral diphosphines and their application in the asymmetric Heck reaction

Five chiral monophosphines and nine planar chiral diphosphines have been synthesised in good yield and enantiopurity by a modular approach; the diphosphines have been reacted with Pd(OAc) 2 and screened for activity in the asymmetric Heck reaction. Graphic

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Bibliographic Details
Published in:Tetrahedron: asymmetry 2003-06, Vol.14 (11), p.1455-1458
Main Authors: Gibson, Susan E., Ibrahim, Hasim, Pasquier, Corinne, Swamy, Vishwanath M.
Format: Article
Language:English
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Summary:Five chiral monophosphines and nine planar chiral diphosphines have been synthesised in good yield and enantiopurity by a modular approach; the diphosphines have been reacted with Pd(OAc) 2 and screened for activity in the asymmetric Heck reaction. Graphic
ISSN:0957-4166
1362-511X
DOI:10.1016/S0957-4166(03)00204-0