Synthesis and characterization of optically active cyclic 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers

A series of racemic and enantiomerically pure 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bri...

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Bibliographic Details
Published in:Tetrahedron: asymmetry 1997-06, Vol.8 (11), p.1825-1831
Main Authors: van Es, J.J.G.S., Biemans, H.A.M., Meijer, E.W.
Format: Article
Language:English
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Summary:A series of racemic and enantiomerically pure 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. A series of racemic and enantiomerically pure 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration as the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge.
ISSN:0957-4166
1362-511X
DOI:10.1016/S0957-4166(97)00185-7