Enantioselective palladium catalyzed allylic substitution using chiral P,N,O Schiff base ligands

Palladium complexes prepared in situ from [Pd(η 3-C 3H 5)Cl] 2 and a number of chiral Schiff ligands having hard and soft donor atoms were evaluated as catalysts for allylic substitution reaction. Enantioselectivity of up to 92% was observed.

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Bibliographic Details
Published in:Journal of molecular catalysis. A, Chemical Chemical, 1999-12, Vol.150 (1), p.23-29
Main Authors: Kwong, Hoi-Lun, Cheng, Leung-Shi, Lee, Wing-Sze
Format: Article
Language:English
Subjects:
Allylic
Catalysis
Catalysts: preparations and properties
Chemistry
Enantioselectivity
Exact sciences and technology
General and physical chemistry
Schiff ligand
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Description
Summary:Palladium complexes prepared in situ from [Pd(η 3-C 3H 5)Cl] 2 and a number of chiral Schiff ligands having hard and soft donor atoms were evaluated as catalysts for allylic substitution reaction. Enantioselectivity of up to 92% was observed.
ISSN:1381-1169
1873-314X
DOI:10.1016/S1381-1169(99)00231-9