Hydroxylation of alkanes catalysed by a chiral μ-oxo diferric complex: a metal-based mechanism

The hydroxylation of alkanes by hydrogen peroxide catalysed by a chiral μ-oxo diferric complex has been demonstrated to be stereospecific and partially enantioselective indicating a metal-based mechanism.

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Bibliographic Details
Published in:Journal of molecular catalysis. A, Chemical Chemical, 2000-05, Vol.156 (1), p.85-89
Main Authors: Mekmouche, Yasmina, Duboc-Toia, Carole, Ménage, Stéphane, Lambeaux, Claude, Fontecave, Marc
Format: Article
Language:English
Subjects:
Alkanes
Hydroxylation
μ-Oxo diferric complex
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Description
Summary:The hydroxylation of alkanes by hydrogen peroxide catalysed by a chiral μ-oxo diferric complex has been demonstrated to be stereospecific and partially enantioselective indicating a metal-based mechanism.
ISSN:1381-1169
1873-314X
DOI:10.1016/S1381-1169(99)00402-1