Hydroxylation of cyclohexane catalyzed by porphyrinatoiron(III) with molecular oxygen: the effect of the photochemical stability of porphyrinatoiron(III) in various solvents

The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride (TPPFeCl) with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeCl in vario...

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Bibliographic Details
Published in:Journal of molecular catalysis. A, Chemical Chemical, 2000-05, Vol.156 (1), p.275-278
Main Authors: Huang, Jin-Wang, Huang, Wei-Zhuang, Mei, Wen-Jie, Liu, Jie, Hu, Shu-Guang, Ji, Liang-Nian
Format: Article
Language:English
Subjects:
Cyclohexane
Hydroxylation
Photochemical stability
Porphyrinatoiron(III)
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Summary:The hydroxylation of cyclohexane catalyzed by 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride (TPPFeCl) with molecular oxygen in various solvents have been preliminarily studied in the case when the catalytic reaction was not carried out in lighttight. The catalytic activity of TPPFeCl in various solvents was found to increase in the following order: acetone
ISSN:1381-1169
1873-314X
DOI:10.1016/S1381-1169(99)00447-1