A new cyanato-bridged polymeric complex [Cd 3(NCO) 6(NH 2CH 2C 5H 4N) 3] n with a zig–zag ladder shaped structure

A new cyanato-bridged polymeric complex [Cd 3(NCO) 6(NH 2CH 2C 5H 4N) 3] n has been synthesized and characterized by X-ray crystallography. There are three cadmium atoms, three chelated 2-(aminomethyl)pyridine and six end-on bridging cyanato groups in the asymmetric unit. Each Cd atom is bonded to o...

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Bibliographic Details
Published in:Inorganic chemistry communications 2001, Vol.4 (8), p.419-422
Main Authors: Choudhury, Chirantan Roy, Dey, Subrata Kumar, Mondal, Nijhuma, Mitra, Samiran, Ozra Ghodsi Mahalli, S., Abdul Malik, K.M.
Format: Article
Language:English
Subjects:
Cadmium complex
Crystal structure
Cyanato bridge
Polymeric complex
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Summary:A new cyanato-bridged polymeric complex [Cd 3(NCO) 6(NH 2CH 2C 5H 4N) 3] n has been synthesized and characterized by X-ray crystallography. There are three cadmium atoms, three chelated 2-(aminomethyl)pyridine and six end-on bridging cyanato groups in the asymmetric unit. Each Cd atom is bonded to one chelated C 5H 4NCH 2NH 2 base and four μ 2-NCO groups in a distorted octahedral environment. Three such independent CdN 6 octahedra share their bridging edges to produce a zig–zag ladder shaped polymeric network extending along a.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(01)00229-5