Synthesis and crystal structure of a novel two-dimensional corrugated coordination polymer

Assembly of 4-aminosalicyclic acid (H 2L) and Ag(I) in MeCN/H 2O gave rise to a novel corrugated sheet polymer {[Ag(HL −)]·H 2O} n . X-ray structural analysis reveals that Ag(I) is coordinated by three different HL − ligands in a distorted trigonal geometry and HL − links three different Ag(I) in a...

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Bibliographic Details
Published in:Inorganic chemistry communications 2002-07, Vol.5 (7), p.487-489
Main Authors: Wang, Ruihu, Hong, Maochun, Zhao, Yingjun, Weng, Jiabao, Cao, Rong
Format: Article
Language:English
Subjects:
Coordination polymer
Crystal structure
Silver(I)
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Summary:Assembly of 4-aminosalicyclic acid (H 2L) and Ag(I) in MeCN/H 2O gave rise to a novel corrugated sheet polymer {[Ag(HL −)]·H 2O} n . X-ray structural analysis reveals that Ag(I) is coordinated by three different HL − ligands in a distorted trigonal geometry and HL − links three different Ag(I) in a μ 3-bridge mode forming a two-dimensional sheet structure with curvature. The separation of the carboxylate-bridged Ag⋯Ag and the distance of adjacent sheets are 2.7720(6) and 4.24 Å, respectively.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(02)00457-4