Triangular barium macrocyclic complex encapsulating perchlorate ions

A novel unique tetraimine Schiff-base macrocyclic barium complex, derived by the template reaction of 4-chloro-2,6-diacetylpyridine with 1,2-diaminoethane, was formed. In the solid state this barium complex exhibits trinuclear motifs with a triangular ring of the macrocyclic ligands and encapsulated...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry communications 1998-03, Vol.1 (3), p.90-92
Main Authors: Fallahpour, Reza-Ali, Neuburger, Markus, Zehnder, Margareta
Format: Article
Language:English
Subjects:
Barium complexes
Crystal structures
Macrocyclic complexes
Schiff base complexes
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A novel unique tetraimine Schiff-base macrocyclic barium complex, derived by the template reaction of 4-chloro-2,6-diacetylpyridine with 1,2-diaminoethane, was formed. In the solid state this barium complex exhibits trinuclear motifs with a triangular ring of the macrocyclic ligands and encapsulated perchlorate anions. Additionally, each macrocycle is functionalised in the `head' framework, and so has the potential of further reactions.
ISSN:1387-7003
1879-0259
DOI:10.1016/S1387-7003(98)00023-9