Selective oxidation of carbohydrates on Nafion ®–TEMPO-modified graphite felt electrodes

The TEMPO-mediated oxidation of carbohydrates was investigated in heterogeneous conditions. The aminoxyl radicals were immobilised in a Nafion ® film on graphite felt electrodes. This selectively gave rise to the corresponding uronic acids. Analytical results targeted towards the kinetics and the st...

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Bibliographic Details
Published in:Electrochemistry communications 2001, Vol.3 (1), p.32-35
Main Authors: Belgsir, E.M., Schäfer, H.J.
Format: Article
Language:English
Subjects:
Carbohydrates
Chemistry
Electrochemistry
Electrosynthesis
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
Oxidation
TEMPO
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Summary:The TEMPO-mediated oxidation of carbohydrates was investigated in heterogeneous conditions. The aminoxyl radicals were immobilised in a Nafion ® film on graphite felt electrodes. This selectively gave rise to the corresponding uronic acids. Analytical results targeted towards the kinetics and the stability of the electrodes are also reported.
ISSN:1388-2481
1873-1902
DOI:10.1016/S1388-2481(00)00137-5