Synthesis and electrochemistry of a novel polyfluorenylidene containing ferrocene units

A novel fluorenylidene containing a ferrocene unit has been electropolymerized. In this polymer, the ferrocene unit is grafted to the main polyfluorenylidene chain as a pendant group. The polymer is electroactive in non-aqueous and aqueous media.

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Bibliographic Details
Published in:Electrochemistry communications 2001-02, Vol.3 (2), p.91-96
Main Authors: Rault-Berthelot, Joëlle, Raoult, Eugène, Pilard, Jean-François, Aoun, Riman, Le Floch, Fabien
Format: Article
Language:English
Subjects:
Anodic polymerization
Applied sciences
Exact sciences and technology
Ferrocenyl pendant unit
Fluorenylidene
Organic polymers
p-doping process
Physicochemistry of polymers
Polyfluorene
Polymerization
Post-functionalization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Description
Summary:A novel fluorenylidene containing a ferrocene unit has been electropolymerized. In this polymer, the ferrocene unit is grafted to the main polyfluorenylidene chain as a pendant group. The polymer is electroactive in non-aqueous and aqueous media.
ISSN:1388-2481
1873-1902
DOI:10.1016/S1388-2481(01)00113-8