Rapid detection of fluoride in potable water using a novel fluorogenic compound 7-O-tert-butyldiphenylsilyl-4-methylcoumarin

• Published in: Analytical chemistry research 2015-12, Vol.6, p.26-31
• Main Authors: Chavali, Ravi, Gunda, Naga Siva Kumar, Naicker, Selvaraj, Mitra, Sushanta K.
• Format: Article
• Language: English
• Subjects: Chemical sensor; Coumarin; Detection; Field deployable; Fluoride
• ISSN: 2214-1812; 2214-1812
• DOI: 10.1016/j.ancr.2015.10.003

In the present work, we have synthesized a new water soluble colorless chemical compound 7-O-tert-butyldiphenylsilyl-4-methylcoumarin (TBDPSC) that releases fluorescent molecules imparting blue fluorescence to the solution, upon interaction with fluoride ions in water. The blue fluorescence can be visualized using simple hand held ultraviolet (UV) lamps. TBDPSC has excellent sensitivity and selectivity towards fluoride and our results indicate that fluoride concentrations as low as 0.2 mg/L can be accurately detected within a few seconds. Fluoride testing with TBDPSC is simple and rapid compared to the conventional methodologies without the requirement of trained personnel. Hence, the present fluoride detection method can be easily field deployable and particularly useful for monitoring water quality in limited resource communities. [Display omitted] •We synthesized a new chemical compound 7-O-tert-butyldiphenylsilyl-4-methylcoumarin (TBDPSC) for fluoride detection.•We demonstrated the excellent sensitivity and selectivity of TBDPSC towards fluoride.•We are able to detect fluoride concentrations as low as 0.2 mg/L within a few seconds.