Isomorphously substituted cerium induced oxygen vacancy and medium basicity in Ni/fibrous silica catalyst for superior low-temperature CO2 methanation

• Published in: Applied catalysis. A, General General, 2025-01, Vol.689, p.120019, Article 120019
• Main Authors: Aziz, M.A., Jalil, A.A., Hassan, N.S., Bahari, M.B., Abdullah, T.A.T., Jusoh, N.W.C., Nagao, Y., Aoki, K., Nishimura, S., Saravanan, Rajendran
• Format: Article
• Language: English
• Subjects: Basicity; Cerium; CO2 methanation; Isomorphous substitution; Oxygen vacancy
• ISSN: 0926-860X
• DOI: 10.1016/j.apcata.2024.120019

A series of promoters (Ce, La, Mo, and Zr) was introduced into the Ni/CHE-SM catalyst by using the impregnation method and tested for CO2 methanation. Among these, Ni-Ce/CHE-SM possessed a high CO2 conversion of 80 % at 250 °C, signifying its potential at low temperature. The superior performance of Ni-Ce/CHE-SM was attributed to the formation of Si-O-Ni and Si-O-Ce species, as confirmed by FTIR-KBr analysis. XPS and CO2-TPD analyses revealed an abundance of oxygen vacancies existed within Ni-Ce/CHE-SM, resulting in enhancement of basicity amount and strength. In addition, Raman analysis showed the existence of three and four silica member rings which was believed that the Si atom be substituted with the Ce atom, thus contributing to create more oxygen vacancies. Hence, additional active sites were provided which enhance the adsorption of reactant molecules and improve the production of CH4, thus emphasizing the greater potential of Ni-Ce/CHE-SM in CO2 methanation application. [Display omitted] •A series of promoters (Ce, La, Mo, and Zr) are incorporated into Ni/CHE-SM.•Ce-promoted catalyst outperforming La, Mo, and Zr-promoted catalysts.•Ni-Ce/CHE-SM achieving 80 % CO2 conversion at low temperature of 250 °C.•Formation of Si-O-Ni and Si-O-Ce improving oxygen vacancies and basicity.•Isomorphous substitution of Ce atom with Si atom creates more oxygen vacancies.