A facile and low-cost synthesis of granulated blast furnace slag-based cementitious material coupled with Fe2O3 catalyst for treatment of dye wastewater

[Display omitted] ► A catalyst of slag-based cementitious material loaded Fe2O3 is firstly synthesized. ► The Fe2O3/ASCM catalyst is firstly used for the photocatalytic degradation of CR. ► The photocatalytic degradation of CR obeys second order reaction kinetics. ► A possible reaction mechanism was...

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Bibliographic Details
Published in:Applied catalysis. B, Environmental Environmental, 2013-07, Vol.138-139, p.9-16
Main Authors: Zhang, Yao Jun, Liu, Li Cai, Ni, Lu Lu, Wang, Bing Li
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Degradation efficiency
Exact sciences and technology
Fe2O3
General and physical chemistry
Photocatalysis
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Reaction kinetics
Slag-based cementitious material
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:[Display omitted] ► A catalyst of slag-based cementitious material loaded Fe2O3 is firstly synthesized. ► The Fe2O3/ASCM catalyst is firstly used for the photocatalytic degradation of CR. ► The photocatalytic degradation of CR obeys second order reaction kinetics. ► A possible reaction mechanism was proposed. A facile and low-cost route was used to synthesize a novel catalyst of alkali-activated granulated blast furnace slag-based cementitious material (ASCM) coupled with Fe2O3 by a three-step reaction of polymerization, ion exchange and impregnation. The FESEM and XRD results revealed that a high compressive strength ASCM with mean particle size about 50nm was synthesized and Fe2O3 covered on ASCM surface in the form of clusters. The photoluminescence peak sharply decreases with increase of Fe2O3 content due to the recombination probabilities of photogenerated electron–hole pairs to be inhibited. The photocatalytic activities for degradation of Congo red (CR) dye were evaluated and the sample of ASCM loaded about 5wt% Fe2O3 showed the highest degradation efficiency under UV irradiation. The photocatalytic degradation of CR in solution obeys second order reaction kinetics and a possible reaction mechanism is proposed.
ISSN:0926-3373
1873-3883
DOI:10.1016/j.apcatb.2013.02.025