Graphitic carbon nitride (g-C3N4) nanocomposites: A new and exciting generation of visible light driven photocatalysts for environmental pollution remediation

• Published in: Applied catalysis. B, Environmental Environmental, 2016-12, Vol.198, p.347-377
• Main Authors: Mamba, G., Mishra, A.K.
• Format: Article
• Language: English
• Subjects: Graphitic carbon nitride; Heterostructures; Nanostructures; Photocatalysis; Z-scheme mechanism
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2016.05.052

Illustration of the numerous applications of g-C3N4 heterostructures. [Display omitted] •Modification of g-C3N4 yield multifunctional materials whose mechanism of action is based on synergy.•Graphitic carbon nitride heterostructures show improved photocatalytic properties than pristine g-C3N4.•Heterojunction and Z-scheme mechanisms are the prominent electron transfer mechanisms in g-C3N4 heterostructures.•Multicomponent semiconductor/g-C3N4 nanocomposites show higher activity than the individual semiconductors.•Incorporation of magnetic nanoparticles in g-C3N4 heterostructures enables easy separation using a magnetic field. Engineering photocatalytic materials for renewable energy generation and environmental decontamination has always been a very exciting prospect to counter the global energy demands and pollution challenges. Graphitic carbon nitride (g-C3N4), a polymeric, metal-free semiconductor with a mild band gap (2.7eV) has become hot-spot in various scientific exploits such as environmental pollution mitigation, energy generation and storage, organic synthesis, sensors, etc. These applications exploit the interesting properties of g-C3N4 such as good visible light absorption, graphene-like structure, good thermal and chemical stability and photocatalytic properties. In this review we begin with an overview of the fundamental aspects of photocatalysis as a pollution remediation strategy. This is followed by an introduction to graphitic carbon nitride as a photocatalyst, preparation strategies and its properties. Subsequently, a comprehensive and critical discussion of the various most recent developments towards enhancing the visible light photocatalytic properties of g-C3N4 for pollution alleviation, selected results and important photocatalytic degradation mechanisms, is given. Summary remarks and future perspective conclude the review.