Development of Carbon-ZrO2 composites with high performance as visible-light photocatalysts

• Published in: Applied catalysis. B, Environmental Environmental, 2017-11, Vol.217, p.540-550
• Main Authors: Bailón-García, Esther, Elmouwahidi, Abdelhakim, Carrasco-Marín, Francisco, Pérez-Cadenas, Agustín F., Maldonado-Hódar, Francisco J.
• Format: Article
• Language: English
• Subjects: Band-gap reduction; Carbon-ZrO2 composites; Total mineralization; Toxicity reduction; Visible light photocatalysts
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2017.05.090

[Display omitted] •New Carbon-ZrO2 composites were synthesized through an one-pot sol-gel synthesis.•Carbon induces the stabilization of well dispersed cubic ZrO2 nanoparticles.•The band gaps for pure ZrO2 is 5.12 but decreases for CZr composites to 2.6eV.•The synergism between carbon-ZrO2 phases makes composites excellent photocatalyts under visible light.•The total mineralization of dye and the elimination of toxicity are achieved. Mesoporous carbon-ZrO2 composites (CZrX) were successfully synthesized by a direct sol-gel procedure. A large battery of experimental techniques is applied for sample characterization. ZrO2 nanoparticles were homogeneously distributed on the carbon supports and stabilized in the cubic phase. The interactions between organic-inorganic phases determine the formation of non-stoichiometric ZrOx oxides, the reduction of the ZrO2 band-gap values and the charge carriers’ recombination, favouring the absorbance of visible light and the photocatalytic behaviour. The total mineralization of the dye and the simultaneous reduction of the toxicity are achieved.