How flue gas impurities affect the electrochemical reduction of CO2 to CO and formate

• Published in: Applied catalysis. B, Environmental Environmental, 2024-02, Vol.341, p.123345, Article 123345
• Main Authors: Van Daele, Sam, Hintjens, Lieven, Hoekx, Saskia, Bohlen, Barbara, Neukermans, Sander, Daems, Nick, Hereijgers, Jonas, Breugelmans, Tom
• Format: Article
• Language: English
• Subjects: CO2 reduction; Electrochemistry; Formate; Impurities
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2023.123345

The electrochemical CO2 reduction offers a promising solution to convert waste CO2 into valuable products like CO and formate. However, CO2 capture and purification remains an energy intensive process and therefore the direct usage of industrially available waste CO2 streams containing SO2, NO and O2 impurities becomes more interesting. This work demonstrates an efficient (Faradaic efficiency > 90 %) and stable performance over 20 h with 200 ppm SO2 or NO in the feed gas stream. However, the addition of 1 % O2 to the CO2 feed causes a significant drop in Faradaic efficiency to C-products due to the competitive oxygen reduction reaction. A potential mitigation strategy is to operate at higher total current density to firstly reduce most O2 and achieve sufficient product output from CO2 reduction. These results aid in understanding the impact of flue gas impurities during CO2 electrolysis which is crucial for potentially bypassing the CO2 purification step. [Display omitted] •20 h performance of CO2 electrolyzer with 200 ppm NO and SO2.•Impact of oxygen in the feed stream during CO2 electrolysis in a continuous flow cell.•Strategy to enhance electrolyzer performance in the presence of oxygen.