Petroleum geochemistry of the Potwar Basin, Pakistan: II – Oil classification based on heterocyclic and polycyclic aromatic hydrocarbons

• Published in: Applied geochemistry 2012-08, Vol.27 (8), p.1655-1665
• Main Authors: Asif, Muhammad, Fazeelat, Tahira
• Format: Article
• Language: English
• Subjects: biomarkers; Earth sciences; Earth, ocean, space; Engineering and environment geology. Geothermics; Exact sciences and technology; Geochemistry; isomers; naphthalene; oils; organic matter; petroleum; phenanthrene; Pollution, environment geology; polycyclic aromatic hydrocarbons; rocks; stable isotopes; steroids
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2012.04.006

[Display omitted] ► Potwar Basin Pakistan contains marine to terrigenous crude oils. ► Aromatic biomarkers reveal oil classification and type of source organic matter. ► Abundance of heterocyclics depends on depositional environments of organic matter. ► Triaromatic/methyl triaromatic steroids show interesting source related distribution. ► Alkyl isomers of naphthalene, phenanthrene, dibenzothiphene, dibenzofuran, fluorene. In a previous study, oils in the Potwar Basin (Upper Indus) of Pakistan were correlated based on the dissimilarity of source and depositional environment of organic matter (OM) using biomarkers and bulk stable isotopes. This study is aimed at supporting the classification of Potwar Basin oils into three groups (A, B and C) using the distribution of alkylnaphthalenes, alkylphenanthrenes, alkyldibenzothiophenes, alkyldibenzofurans, alkylfluorenes, alkylbiphenyls, triaromatic steroids, methyl triaromatic steroids, retene, methyl retenes and cadalene. The higher relative abundance of specific methyl isomers of naphthalene and phenanthrene and the presence of diagnostic aromatic biomarkers clearly indicate the terrigenous and oxic depositional environment of OM for group A oil. Group B and C oils are of marine origin and the aforementioned heterocyclic and polycyclic aromatic hydrocarbons (HCs) differentiate them clearly into two different groups. The relative percentages of heterocyclic aromatic HCs reveal that the distribution of these compounds is controlled by the depositional environment of the OM. Sulfur-containing heterocyclic aromatic HCs are higher in crude oils generated from source rocks deposited in suboxic depositional environments, while oxygen-containing heterocyclic aromatic HCs in combination with alkylfluorenes are higher in marine oxic and deltaic oils. Biomarker and aromatic HC parameters do not indicate significant differences in the thermal maturity of Potwar Basin oils. Triaromatic and methyl triaromatic steroids support the division of Potwar Basin oils into the three groups and their relative abundances are related to source OM rather than thermal maturity. Significantly higher amounts of C20 and C21 triaromtic steroids and the presence or absence of long chain triaromatic steroids (C25, C26, C27, and C28) indicates that these compounds are probably formed from different biological precursors in each group. Different isomers of methyl substituted triaromatic steroids are present only for short chain compounds (C20–C2