Uptake of arsenate by aluminum (hydr)oxide coated red scoria and pumice

• Published in: Applied geochemistry 2017-03, Vol.78, p.83-95
• Main Authors: Asere, Tsegaye Girma, De Clercq, Jeriffa, Verbeken, Kim, Tessema, Dejene A., Fufa, Fekadu, Stevens, Christian V., Du Laing, Gijs
• Format: Article
• Language: English
• Subjects: Adsorption; Aluminum; Arsenic; Pumice; Red scoria
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2016.12.013

The development of cost effective and environmentally benign adsorbents for arsenic removal is absolutely required due to arsenic contamination of water sources in many regions around the globe. The use of materials which are locally available in the affected regions is important for successful implementation of the developed technologies in rural areas. In this regard, we treated volcanic rocks (red scoria and pumice) locally available in Ethiopia with an aluminum sulphate solution and evaluated these materials for their capacity to remove As(V) from aqueous systems. The adsorbents were characterized using ICP-OES, EDX, SEM and BET. The experimental sorption data fitted well a Freundlich isotherm and the pseudo-second-order model was found to be more suitable than the pseudo-first-order model to describe the adsorption kinetics. The Langmuir maximum adsorption capacity was 0.18 mg/g for aluminum-treated red scoria (Al-Rs) and 2.68 mg/g for aluminum-treated pumice (Al-Pu). The effect of pH, adsorbent dose, initial As(V) concentration and interfering ions on arsenic adsorption were studied. The leaching of aluminum from the adsorbent during the adsorption process was also investigated. Results of column experiments indicated that Al-Pu is suitable to treat low concentration of As(V) contaminated water. The Al-Pu adsorbent is recyclable with only about 9% loss of its original efficiency after the 3rd adsorption cycle (99.5%–90.2%). The data obtained from both batch and column studies indicate that Al-Rs and Al-Pu remove As(V) effectively from aqueous systems, with the latter being more efficient. •Aluminum oxide coated volcanic rocks are used as adsorbent for As(V).•The adsorbents remove As(V) from water rapidly and effectively in a wide pH range.•The kinetic data fitted well to the pseudo-second-order model.•Other anions could not interfere As(V) adsorption except phosphate.•The adsorbents can be used for several recycles.