Erosion behaviour of raw bentonites under compacted and confined conditions: Relevance of smectite content and clay/water interactions

The quantification of colloid erosion from compacted bentonite barrier, in a high-level waste repository, is considered especially relevant because erosion may compromise its performance and because eroded colloids may contribute to radionuclide transport. The erosion behaviour of different raw bent...

Full description

Saved in:
Bibliographic Details
Published in:Applied geochemistry 2018-07, Vol.94, p.11-20
Main Authors: Alonso, Ursula, Missana, Tiziana, Fernández, Ana María, García-Gutiérrez, Miguel
Format: Article
Language:English
Subjects:
Bentonite
Clay/water interactions
Colloids
Erosion
Radioactive waste
Smectite
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The quantification of colloid erosion from compacted bentonite barrier, in a high-level waste repository, is considered especially relevant because erosion may compromise its performance and because eroded colloids may contribute to radionuclide transport. The erosion behaviour of different raw bentonites, compacted at high density, was analysed in a confined system under favourable chemical conditions. A complete physical and geochemical characterisation of clays was carried out to overall relate clay physico-chemical characteristics and structure to their erosion behaviour. The mass eroded under compacted and confined conditions were in all cases lower than those obtained under free-dispersed conditions; indicating that compacted and confined conditions were limiting erosion. Maximum erosion was below a 1% of the initial mass. Results clearly showed that clay erosion under compacted state was hindered for those bentonites with high content of bivalent cations in exchangeable positions ((Ca + Na) > 90%), low smectite content (Sm.  0.1 e/h.u.c.). In addition, it was demonstrated that, at high solid to liquid ratios, dissolution of salts present in the clay and cation exchange reactions decrease the extent of erosion. •Erosion behaviour of raw bentonites was analysed under compacted and confined conditions.•Mass eroded from compacted and confined bentonites was lower than 1% of the initial mass.•Bentonites with high smectite content and/or low tetrahedral charge suffered more erosion.•Dissolution of salts present in the clay and clay/water interactions decrease erosion.
ISSN:0883-2927
1872-9134
DOI:10.1016/j.apgeochem.2018.04.012