Neptunium(V) transport in granitic rock: A laboratory scale study on the influence of bentonite colloids

• Published in: Applied geochemistry 2019-04, Vol.103, p.31-39
• Main Authors: Elo, O., Hölttä, P., Kekäläinen, P., Voutilainen, M., Huittinen, N.
• Format: Article
• Language: English
• Subjects: Bentonite colloids; Column experiments; Granitic rock; Neptunium(V); Sorption
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2019.01.015

In the present study neptunium(V) uptake by crystalline granitic rock (Kuru Grey granite) and the role of stable and mobile bentonite colloids (MX-80) on the migration of neptunium(V) was investigated. Two different experimental setups were utilized, batch-type experiments under stagnant conditions and column experiments under flowing water conditions. The uptake of 10−6 M neptunium(V) by 40 g/L crushed granite in 10 mM NaClO4 was found to be pH-dependent, whereas neptunium(V) uptake by MX-80 bentonite colloids (0.08–0.8 g/L) was pH-independent up to a pH-value of approximately 11. Column experiments were conducted in the presence and absence of colloids at two pH values (pH = 8 and 10) and two flow rates (0.3 and 0.8 mL/h) in 10 mM NaClO4. The injected neptunium(V) concentration was 2 × 10−4 M and the colloid concentration ranged from 0.08 to 0.32 g/L. The properties of the flow field in the columns were investigated with a conservative chloride tracer, at the same two flow rates of 0.8 and 0.3 mL/h. The resulting breakthrough curves were modeled using the analytical solution of advection–matrix diffusion equation. A tailing of neptunium(V) breakthrough curves in comparison to the conservative tracer was observed, which could be explained by a slightly higher retardation of neptunium(V) in the column caused by sorption on the granite. The sorption was in general lower at pH 8 than at pH 10. In addition, the tailing was almost identical in the absence and presence of MX-80 bentonite colloids, implying that the influence of colloids on the neptunium(V) mobility is almost negligible. •The influence of MX-80 bentonite colloids on Np(V) migration in granitic media was investigated.•Sorption of Np(V) on granite was found to be pH-dependent, while a pH-independent uptake by MX-80 colloids was observed.•Np(V) migration in the absence and presence of MX-80 bentonite colloids was investigated in granite drill core columns.•A clear influence of bentonite colloids on Np(V) breakthrough was not observed.•The breakthrough was modeled with the analytical solution of advection–matrix diffusion equation.