Riverine 129I dynamics during high-flow events on the Abukuma River in Fukushima

• Published in: Applied geochemistry 2024-10, Vol.173, p.106134, Article 106134
• Main Authors: Wakiyama, Yoshifumi, Matsumura, Masumi, Matsunaka, Tetsuya, Hirao, Shigekazu, Sasa, Kimikazu
• Format: Article
• Language: English
• Subjects: Accelerator mass spectrometry; Cesium-137; Fukushima; Iodine-129; Suspended solids
• ISSN: 0883-2927
• DOI: 10.1016/j.apgeochem.2024.106134

This study presents the riverine 129I concentrations and fluxes during high-flow events. The river water samples obtained by a previous study were subjected to 129I analyses. River water samples were collected at the midstream of the Abukuma River for five and seven times during high-flow events in July 2018 and October 2018, respectively. Suspended solids and filtered water samples were measured for 129I/127I ratios using an accelerator mass spectrometer system and for 127I concentrations using ICP-MS. Aggregated mean values of dissolved 129I concentration and 129I concentrations in suspended solids were 0.11 μBq/L (n = 12) and 0.60 mBq/kg (n = 12), respectively. Corresponding values of 129I/127I ratios were in 2.2 × 10−9 (n = 12) and 3.7 × 10−9 (n = 12), respectively. These concentrations and ratios were comparable to those at the background level before the Fukushima Dai-ichi nuclear power plant accident. Positive correlations with dissolved 137Cs and Cl− concentrations suggested that the dissolved 129I concentration decreased due to dilution of the river water during the events. A positive correlation with total carbon content suggested that organic matter contents determine 129I concentrations in suspended solids. The total 129I fluxes during JUL18 and OCT18 were 9.9 × 103 and 2.2 × 104 Bq, respectively. Although dissolved 129I was predominant under low-flow conditions, the particulate 129I flux increased by one or two orders of magnitude during the peak water discharge phases. These results underline the importance of particulate 129I dynamics during high-flow events for quantitative evaluation of the 129I cycle. •Riverine particulate and dissolved 129I concentrations and fluxes were evaluated.•Riverine 129I concentrations were in pre-accidental level in the studied catchment.•Positive correlation was found between carbon content and 129I in suspended solids.•Particulate 129I flux can exceed that of dissolved at peak water discharge phases.