Significant change of local atomic configurations at surface of reduced activation Eurofer steels induced by hydrogenation treatments

• Published in: Applied surface science 2017-04, Vol.402, p.114-119
• Main Authors: Greculeasa, S.G., Palade, P., Schinteie, G., Kuncser, A., Stanciu, A., Lungu, G.A., Porosnicu, C., Lungu, C.P., Kuncser, V.
• Format: Article
• Language: English
• Subjects: Atomic interdiffusion; CEMS; Eurofer alloy; Hydrogenation; XPS
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2017.01.056

•Engineering of Eurofer slab properties by hydrogenation treatments.•Hydrogenation modifies significantly the local atomic configurations at the surface.•Hydrogenation increases the expulsion of the Cr atoms toward the very surface.•Approaching binomial atomic distribution by hydrogenation in the next surface 100nm. Reduced-activation steels such as Eurofer alloys are candidates for supporting plasma facing components in tokamak-like nuclear fusion reactors. In order to investigate the impact of hydrogen/deuterium insertion in their crystalline lattice, annealing treatments in hydrogen atmosphere have been applied on Eurofer slabs. The resulting samples have been analyzed with respect to local structure and atomic configuration both before and after successive annealing treatments, by X-ray diffractometry (XRD), scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS), X-ray photoelectron spectroscopy (XPS) and conversion electron Mössbauer spectroscopy (CEMS). The corroborated data point out for a bcc type structure of the non-hydrogenated alloy, with an average alloy composition approaching Fe0.9Cr0.1 along a depth of about 100nm. EDS elemental maps do not indicate surface inhomogeneities in concentration whereas the Mössbauer spectra prove significant deviations from a homogeneous alloying. The hydrogenation increases the expulsion of the Cr atoms toward the surface layer and decreases their oxidation, with considerable influence on the surface properties of the steel. The hydrogenation treatment is therefore proposed as a potential alternative for a convenient engineering of the surface of different Fe-Cr based alloys.