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High-performance aqueous rechargeable sulfate- and sodium-ion battery based on polypyrrole-MWCNT core-shell nanowires and Na0.44MnO2 nanorods

[Display omitted] •Novel aqueous rechargeable sulfate- and sodium-ion battery is demonstrated.•MWCNT-polypyrrole nanowire and Na0.44MnO2 nanorod are used as anode and cathode.•Full cell exhibits better performance at relatively high-rate charge-discharge. Aqueous rechargeable sodium-ion batteries (A...

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Bibliographic Details
Published in:Applied surface science 2018-07, Vol.446, p.131-138
Main Authors: Lim, Hana, Jung, Ji Hea, Park, Young Min, Lee, Ho-Nyun, Kim, Hyun-Jong
Format: Article
Language:English
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Summary:[Display omitted] •Novel aqueous rechargeable sulfate- and sodium-ion battery is demonstrated.•MWCNT-polypyrrole nanowire and Na0.44MnO2 nanorod are used as anode and cathode.•Full cell exhibits better performance at relatively high-rate charge-discharge. Aqueous rechargeable sodium-ion batteries (ARSBs) have the potential for application in large-scale electric energy storage systems owing to the safety of the non-flammable aqueous electrolyte and the natural abundance of sodium resources. Herein, we demonstrate the high performance of an aqueous rechargeable sulfate- and sodium-ion battery based on a MWCNT-polypyrrole core–shell nanowire anode and a Na0.44MnO2 nanorod cathode in a 1 M aqueous Na2SO4 electrolyte. Because the charge-discharge process involves the simultaneous uptake and release of both sulfate anions and sodium cations, it offers a wider choice of electrode materials for use at high voltages. The MWCNT-polypyrrole core-shell nanowire//Na0.44MnO2 nanorod full cell delivered excellent discharge capacities of 99.2 mA h g−1 and 87.2 mA h g−1 with a high voltage of 1.6 V at the charge-discharge current densities of 100 mA g−1 and 3000 mA g−1, respectively. When compared with previous ARSBs, the aqueous rechargeable sulfate- and sodium-ion battery shows much better performance at relatively high charge–discharge rates, making it suitable for large-scale energy storage applications.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2018.02.021