Large energy density at high-temperature and excellent thermal stability in polyimide nanocomposite contained with small loading of BaTiO3 nanofibers

• Published in: Applied surface science 2018-11, Vol.458, p.743-750
• Main Authors: Hu, Penghao, Sun, Weidong, Fan, Mingzhi, Qian, Jianfeng, Jiang, Jianyong, Dan, Zhenkang, Lin, Yuanhua, Nan, Ce-Wen, Li, Ming, Shen, Yang
• Format: Article
• Language: English
• Subjects: Energy density; High-temperature; Nanocomposite; Nanofibers; Thermal stability
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2018.07.128

[Display omitted] •Fabricates polyimide nanocomposite contained with BaTiO3 nanofibers by portable method.•The improvement on the dielectric properties induced by small loading of nanofibers is effective.•Obtains enhanced energy density in the nanocomposite at high temperature.•Realize better energy storage performances with high thermal stability than BOPP. Dielectric capacitors are always faced with high temperature in many application cases, so the applicability of high temperature is highly desired for dielectrics besides large energy storage density. Polyimide is a widely used engineering polymer with excellent thermotolerance and ceramic nanofillers with large aspect ratio are effective in improving the dielectric properties of polymer nanocomposite. In this work, PI nanocomposite films contained with BaTiO3 nanofibers prepared via electrospinning were fabricated by solution casting and thermal imidization process. The dielectric properties of the nanocomposites were investigated from room temperature to 200 °C. With the introduction of BaTiO3 nanofibers, the dielectric permittivity was enlarged with weak increase on dielectric loss in nanocomposites. The breakdown strength (550 kV/mm) as well as discharged energy density (5.82 J/cm3) was largely enhanced in BaTiO3/PI nanocomposite contained with 1 vol% nanofibers. Benefited from the decreased leakage current and improved thermal conduction induced by BaTiO3 nanofibers, the 1 vol% BaTiO3/PI nanocomposite also represented high energy efficiency and excellent thermal stability. The discharged energy density of above 2.1 J/cm3 and near 4 J/cm3 with efficiency larger than 90% are stable from room temperature to 150 °C and to 100 °C respectively. The high temperature applicability of the present material makes it much promising in fabricating dielectric energy storage devices applied in hot environment.