Photocatalytic degradation of 4-chlorophenol with the use of FTO/TiO2/SrTiO3 composite prepared by microwave-assisted hydrothermal method

• Published in: Applied surface science 2019-03, Vol.470, p.991-1002
• Main Authors: Łęcki, Tomasz, Zarębska, Kamila, Sobczak, Kamil, Skompska, Magdalena
• Format: Article
• Language: English
• Subjects: 4-Chlorophenol photodecomposition; Electron lifetime; Microwave-assisted hydrothermal synthesis; Photocatalysis; Photoelectrochemical properties; SrSiO3; TiO2/SrTiO3
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2018.11.200

[Display omitted] •Morphology of TiO2/SrTiO3 composite depends on concentration of Sr2+ ions used in synthesis.•Formation of TiO2/SrTiO3 interface improves the electron-hole recombination rate.•The TiO2/SrTiO3 is an efficient photocatalyst in 4-chlorophenol degradation.•Photodegradation of 4-CP is mediated mainly by the hydroxyl radicals.•SrSiO3 deposited on the back side of the glass plate is excellent adsorbent for cationic dyes. Microwave-assisted hydrothermal method was applied to obtain SrTiO3 photocatalyst by transformation of a thin TiO2 layer deposited on the conducting solid substrate (FTO-glass) via dissolution-precipitation reaction in alkaline solution. The influence of Sr2+ ions concentration on crystallinity, composition as well as photoelectrochemical and photocatalytic properties of the resultant materials was investigated. The XRD studies indicated the presence of some amount of co-deposited SrSiO3 due to reaction of metasilicates released from the glass substrate (not covered with FTO film). However, the process of glass dissolution was substantially prevented by protection of the back side of the sample with a Teflon tape. The best activity in photodecomposition of 4-chlorophenol under irradiation with 365 nm diode was obtained for FTO/TiO2/SrTiO3 composite fabricated in 6 h synthesis in the solution containing 0.1 M Sr(NO3)2, at temperature of 180 °C. The photoelectrochemical properties of the composites and FTO/TiO2 electrode were studied in the solution of Na2SO4 under illumination with a xenon lamp. The increased photocurrent density and longer electron lifetime for the hybrid system in comparison to those of TiO2 was discussed in terms of suppressed recombination rate due to formation of TiO2/SrTiO3 interface. It was also found that the side product, SrSiO3, reveals an excellent adsorption properties with respect to methylene blue and therefore, the system SrTiO3/TiO2/FTO/glass/SrSiO3 may be used as bifunctional composite for adsorption and photocatalysis.