Ab-initio approach to the stability and the structural, electronic and magnetic properties of the (001) Znfe2O4 surface terminations

We present a Density Functional Theory (DFT) based study of the structural and magnetic properties of the (001) surface of the semiconducting oxide ZnFe2O4 (spinel structure). The calculations were performed using the DFT based ab initio plane wave and pseudopotential method as implemented in the Qu...

Full description

Saved in:
Bibliographic Details
Published in:Applied surface science 2020-01, Vol.499, p.143859, Article 143859
Main Authors: Rodríguez, K.L. Salcedo, Quintero, J.J. Melo, Medina Chanduví, H.H., Rebaza, A.V. Gil, Faccio, R., Adeagbo, W.A., Hergert, W., Torres, C.E. Rodríguez, Errico, L.A.
Format: Article
Language:English
Subjects:
Ab initio
Electronic structure
Magnetic response
Surface termination
Zn-ferrite
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We present a Density Functional Theory (DFT) based study of the structural and magnetic properties of the (001) surface of the semiconducting oxide ZnFe2O4 (spinel structure). The calculations were performed using the DFT based ab initio plane wave and pseudopotential method as implemented in the Quantum Espresso code. The all electron Full-potential linearized-augmented-plane-wave method (FP-LAPW) was also employed to check the reproducibility of the plane wave method. In both calculations the DFT+U methodology was employed and different (001) surface terminations of ZnFe2O4 were studied. We find that the surface terminated in Zn is the stable one. For all the (001) surface terminations our calculations predict that the Zn-Fe cationic inversion (anti-sites), which are defects in bulk ZnFe2O4, becomes stable and an integral part of the surface. Also, a ferrimagnetic behavior is predicted for the case of anti-sites in the superficial layer. Our results for different properties of the surface of ZnFe2O4 are compared with those obtained in bulk samples and those reported in the literature. [Display omitted] •DFT determination of the stability and reconstruction of the (001) terminations of ZnFe2O4•The Zn termination is predicted to be the stable one.•Cationic inversion becomes stable and an integral part of the surface.•Inversion strengthened the magnetic interactions and the ferrimagnetic behavior.•The ferrimagnetic behavior of an otherwise paramagnetic oxide is explained.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2019.143859