Shifting the band gap from UV to visible region in cerium oxide nanoparticles

• Published in: Applied surface science 2020-10, Vol.528, p.146860, Article 146860
• Main Authors: Thill, Alisson S., Lobato, Francielli O., Vaz, Mauricio O., Fernandes, Willians P., Carvalho, Vágner E., Soares, Edmar A., Poletto, Fernanda, Teixeira, Sérgio R., Bernardi, Fabiano
• Format: Article
• Language: English
• Subjects: Band gap engineering; Cerium oxide; High surface area; Hydrogen production; Oxygen vacancy; Solar energy
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2020.146860

[Display omitted] •Band gap engineering of CeO2-x nanoparticles shifts absorption from UV to visible.•CeO2-x nanoparticles of high surface area and surface O vacancy population used for H2 production.•Improving the activity of CeO2-x nanoparticles for the photocatalytic H2 production. High surface area cerium oxide (CeO2-x) nanoparticles (S = 170 m2/g) were synthesized by the precipitation method with a narrow band gap (2.73 ± 0.03 eV). In comparison to typical band gap values for cerium oxide, it presents a red shift in the light absorption spectrum from UV to visible region. X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Absorption Spectroscopy (XAS), X-ray Photoelectron Spectroscopy (XPS) and Ultraviolet Photoelectron Spectroscopy (UPS) measurements were conducted aiming to elucidate this promising property for photocatalytic applications of the nanoparticles synthesized. It was obtained that the high structural disorder and O vacancy population of the nanoparticles synthesized are responsible for the narrow band gap found. Furthermore, the CeO2-x nanoparticles were applied to the photocatalytic H2 production reaction and presented activity 10 times higher than the commercial CeO2-x standard, besides a much better performance than typical results found for CeO2-x in the literature.