Antiferromagnetic coupling in the initial stages of the MnN epitaxial growth on the CrN (001) surface

• Published in: Applied surface science 2022-01, Vol.573, p.151451, Article 151451
• Main Authors: Moreno H., J.C., Ponce-Pérez, R., Cocoletzi, Gregorio H., Takeuchi, Noboru
• Format: Article
• Language: English
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2021.151451

[Display omitted] •Mn transforms from paramagnetic to ferromagnetic system.•The results suggest the possibility of growing θ-MnN epitaxially.•Double MnN layer exhibits an antiferromagnetic behavior, with the magnetic moments coupled parallel and alternating along c.•Exchange bias effect is manifested in the interface CrN/MnN. Spin polarized first principles calculations have been performed to study the structural and electronic properties, and spin coupling of the MnN deposit on the CrN (001) surface. Results indicate that Mn may transform from a paramagnetic to a ferromagnetic system, when adsorbed on a surface. Also, the first CrN layer switches from antiferromagnetic to ferromagnetic alignment. Surface formation energies show that epitaxial growth of θ-MnN on the CrN (001)-(1x1) surface is favorable for N-rich conditions and intermediate conditions. The double MnN layer exhibits an antiferromagnetic behavior, with the magnetic moments coupled parallel and alternating along c. Moreover, the exchange bias effect is manifested in the first CrN layer. The calculated projected densities of states spectra show a half metallic character in the first CrN layer. The Mn magnetic moments are in the range of 2.8–3.3 μB. This work identifies an antiferromagnetic system for possible applications in spintronics.