Excellent photocatalytic activity of MoO3-adorned g-C3N4 systems: Construction of S-scheme heterojunction

• Published in: Applied surface science 2022-12, Vol.604, p.154512, Article 154512
• Main Authors: Luo, Jianmin, Han, Haonan, Wu, Jingwu, Wang, Xinlei, Feng, Junli, Toan, Sam, Wang, Lei, Lai, Yinlong
• Format: Article
• Language: English
• Subjects: MoO3/g-C3N4; Photocatalytic degradation; Rhodamine B; S-scheme heterojunction; Theoretical calculation
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2022.154512

[Display omitted] •The S-scheme heterojunction of MoO3/g-C3N4 with rich N-defects was prepared by one-step calcination method.•The improvement of photocatalytic removal of rhodamine B and Cr (VI) use MoO3/g-C3N4 as catalyst.•The transfer pathways of photocarriers in the interface of MoO3/g-C3N4 were revealed based on the theoretical calculations. To alleviate harmful pollutants in water, photocatalytic technology, which offers green degradation of pollutants, is being used. The g-C3N4 is a metal-free organic polymer semiconductor photocatalyst widely used in photocatalysis. However, some drawbacks have limited its practical application. Thus, constructing of semiconductor heterojunction with appropriate band structure to improve photocatalysis activity for g-C3N4is an effective and common means to overcome the drawbacks. Therefore, in this study, MoO3/g-C3N4 (MoCN) was prepared via the one-step calcination method. The photocatalytic performance of the composite was evaluated via photocatalytic degradation of rhodamine B (RhB) and the data revealed that the 3MoCN composite semiconductor greatly enhanced the activity (about 6.3 times) of pure g-C3N4 toward the degradation of RhB. Meanwhile, the free radical masking experiments suggested O2− as the major oxidizing species in the MoCN system. The specific area of the composite system of MoCN was 3.7-fold higher than that of pure g-C3N4. Furthermore, the photoelectric properties tests and DFT demonstrated improved photoactivity of MoO3/g-C3N4 due to the movement of Fermi levels and built-in electric field close to the S-scheme heterojunction interface. Our work demonstrated a simple strategy to prepare efficient photocatalysts for environmental remediation.