In-situ growth of Cs2AgBiBr6 perovskite nanocrystals on Ti3C2Tx MXene nanosheets for enhanced photocatalytic activity

• Published in: Applied surface science 2023-06, Vol.621, p.156877, Article 156877
• Main Authors: Cheng, Shanshan, Chen, Xu, Wang, Meng, Li, Gaoqiang, Qi, Xiaofeng, Tian, Yongtao, Jia, Mochen, Han, Yanbing, Wu, Di, Li, Xinjian, Shi, Zhifeng
• Format: Article
• Language: English
• Subjects: Cs2AgBiBr6 nanocrystals; Heterostructures; Photocatalysis; Ti3C2Tx MXenes; Visible light
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2023.156877

[Display omitted] •The Cs2AgBiBr6 nanocrystals are in situ grown on Ti3C2Tx MXene nanosheets to constitute Cs2AgBiBr6/MXenes nanocomposites.•Schottky heterojunctions at the Cs2AgBiBr6/MXenes interface could promote electron-hole separation and increase the carrier concentration.•The enhanced specific surface area could function as the reaction site for improving surface reaction kinetics.•The introduction of Ti3C2Tx nanosheets significantly enhanced the visible-light photocatalytic activity of Cs2AgBiBr6 NCs, which is about 4.7 times higher than that of pristine Cs2AgBiBr6 NCs. Photocatalytic degradation of organic dyes is an efficient, safe and environmentally-friendly technique for improving environmental purification. Exploring high-quality and low-cost photocatalysts for photocatalytic degradation with enhanced light harvesting capability and efficient charge separation and transport remains a challenge. Herein, we utilize the two-dimensional (2D) MXene, Ti3C2Tx nanosheets as a high efficiency co-catalyst to construct the Cs2AgBiBr6/Ti3C2Tx Schottky heterostructure by in-situ growth of Cs2AgBiBr6 perovskite NCs on Ti3C2Tx nanosheets via thermal injection method. The optimized Cs2AgBiBr6/Ti3C2Tx nanocomposites show a substantially enhanced organic dye degradation rate, which is ∼4.7 times higher than that of the pristine Cs2AgBiBr6 NCs. Such outstanding photocatalytic activity of Cs2AgBiBr6/Ti3C2Tx nanocomposites stems from the strong interaction between Cs2AgBiBr6 NCs and highly conductive 2D Ti3C2Tx nanosheets, a large interface contact area, and the favorable Fermi level alignment, which significantly promote the charge transfer and separation efficiency while suppressing the electron-hole recombination. More importantly, the Cs2AgBiBr6/MXenes–based photocatalysts exhibit good repeatability and long-term stability. It is demonstrated that this work will guide the construction of high-efficiency and stable photocatalytic materials for environmental purification.