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Engineering two-dimensional SnC/HfSSe heterojunction as a direct Z-scheme photocatalyst for water splitting hydrogen evolution
Developing robust water-splitting photocatalyst remains a pivotal challenge for the conversion of solar energy to hydrogen fuel. Herein, we report SnC/HfSSe heterojunctions to be a competitive direct Z-scheme photocatalysts with HfSSe acting as an oxidant and SnC as a reductant for water-splitting h...
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Published in: | Applied surface science 2023-07, Vol.626, p.157247, Article 157247 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Developing robust water-splitting photocatalyst remains a pivotal challenge for the conversion of solar energy to hydrogen fuel. Herein, we report SnC/HfSSe heterojunctions to be a competitive direct Z-scheme photocatalysts with HfSSe acting as an oxidant and SnC as a reductant for water-splitting hydrogen generation by employing the first-principles calculations. The photogenerated electron–hole migration logically follows the Z-scheme path due to the large interlayer built-in electric field, small interlayer bandgap, proper band edge alignment, and high interlayer carrier recombination. The overpotential is appropriate to the oxygen evolution reaction (OER), while the overpotential is slightly large to the hydrogen envolution reaction (HER) so that the incident photon energy above the band gap of the components is required for the HER. The heterojunctions have excellent visible light absorption, exhibiting the remarkable red shift and stronger light absorption with respect to the two components of the heterojunction. Moreover, the heterojunction exhibits an outstanding solar-to-hydrogen (STH) efficiency as high as 27% in extremely acidic solution.
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•Jannus HfSSe could be assembled with SnC into the stable SnC/HfSSe heterojunction.•The heterojunction is shown to be a direct Z-scheme photocatalyst.•The heterojunction has the appropriate overpotentials for the redox reactions.•The heterojunction exhibits excellent visible light absorption and outstanding solar-to-hydrogen efficiency. |
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ISSN: | 0169-4332 1873-5584 |
DOI: | 10.1016/j.apsusc.2023.157247 |