Out-of-plane preferential growth of 2D molybdenum diselenide nanosheets on laser-induced periodic surface structures

• Published in: Applied surface science 2024-10, Vol.669, p.160567, Article 160567
• Main Authors: Fernández García, A., Ariza, R., Solis, J., Agulló-Rueda, F., Manso Silvan, M., Garcia-Lechuga, M.
• Format: Article
• Language: English
• Subjects: 2D nanosheets; Isothermal closed space vapor deposition; Molybdenum diselenide; SERS; Ultrashort laser structuring
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2024.160567

[Display omitted] •Demonstrating Control of 2D MoSe2 Growth and Orientation on laser-structured substrates (dielectric, semiconductor, and metals).•Out-of-plane Orientation on Active Edge Sites Leading to Enhanced Raman Signals.•Laser-induced periodic surface structures offer a versatile and Scalable Strategy for Tailoring Properties of 2D Materials. In this study, we explore the morphology and orientation of molybdenum diselenide, a Van der Waals 2D material, through isothermal closed space vapor deposition on both pristine and laser-structured substrates. Laser structuring is conducted on dielectric (sapphire), semiconductor (silicon), and conductive (titanium nitride) substrates using ultrashort laser pulses, resulting in smooth topographic changes such as laser-induced periodic surface structures (LIPSS) or selective ablation. Scanning electron microscopy (SEM) reveals the pivotal role of surface structuring in the growth of out-of-plane MoSe2 nanosheets. This effect is particularly pronounced on monocrystalline substrates like sapphire and silicon, exhibiting in-plane growth on pristine substrates. Additionally, Raman spectroscopy confirms the vertical orientation of flakes on structured substrates and highlights the presence of active edge sites by demonstrating an increased abundance of deposited material. Overall, our findings emphasize the controllability of directing the growth of MoSe2 flakes through appropriate pre-treatment of the substrate, with potential applications in various fields, including Surface-Enhanced Raman Scattering (SERS). Furthermore, the scalability, reproducibility, and applicability to any substrate make ultrashort laser structuration a promising general strategy for orienting 2D materials.