Characteristics and source apportionment of non-polar organic compounds in PM2.5 from the three megacities in Yangtze River Delta region, China

• Published in: Atmospheric research 2021-04, Vol.252, p.105443, Article 105443
• Main Authors: Cao, Fang, Zhang, Yi-Xuan, Lin, Xin, Zhang, Yan-Lin
• Format: Article
• Language: English
• Subjects: Health risk; n-Alkanes; Organic aerosols; PAHs; PM2.5; Source apportionment
• ISSN: 0169-8095; 1873-2895
• DOI: 10.1016/j.atmosres.2020.105443

Fine particulate matter samples (PM2.5) were collected from the three megacities of the Yangtze River Delta (i.e., Shanghai, Hangzhou, and Nanjing) during November 11 to December 6, 2016. Organic carbon (OC), elemental carbon (EC), and four types of non-polar organic compounds such as polycyclic aromatic hydrocarbons (PAHs), n-alkanes, hopanes and steranes were analyzed in the samples. The average PM2.5 mass concentrations were 47.0, 64.2 and 45.5 μg m−3 in Shanghai, Hangzhou and Nanjing, respectively. OC and EC concentrations were 4.47 and 0.78 μg m−3, 15.38 and 2.97 μg m−3, 10.35 and 2.06 μg m−3, respectively. n-Alkanes accounted for the largest abundance of the identified non-polar organic compounds, followed by PAHs, hopanes and steranes. The positive matrix factorization (PMF) analysis demonstrated that vehicular emissions, coal burning and industrial emissions were the most important sources. Vehicle exhaust was the major source of emissions in Shanghai (61.0%) and Hangzhou (45.3%), whereas coal combustion emissions was dominant (48.8%) in Nanjing. In addition, the estimated lifetime cancer risk (ILCR) values exposed to PAHs for adults (6.54 × 10−5) and children (7.32 × 10−6) suggested that PAHs levels in this region pose potential health risks. Combining the health risk model with PMF further concluded that vehicular emissions (49.0%) and coal burning (35.7%) were the two major sources that contribute to the ILCR values in these three cities. •Characteristics and source apportionment of NPOCs from three megacities in the YRD were studied.•NPOCs with unique sources were used to track the source of the aerosols.•Vehicular emissions and coal burning were most important contributors of NPOCs.•Polycyclic aromatic hydrocarbons pose a greater health risk to adult than children.•Combining the health risk model and PMF to reveal the contribution of each source to health risk.