Boron-graphene composite for efficient electromagnetic interference shielding with strong strength and near-zero thermal expansion

• Published in: Carbon (New York) 2024-09, Vol.228, p.119318, Article 119318
• Main Authors: Li, Jie, Xing, Changsheng, Shuang, Jiaxu, Wu, Yunzhong, Zhang, Tong, Liu, Bin, Guan, Yekang, Sheng, Jie, Ren, Qingtan, Wang, Yongkang, Wang, Lidong, Fei, Weidong
• Format: Article
• Language: English
• Subjects: Boron; Electromagnetic shielding; Graphene; Multifunctional composite; Near-zero thermal expansion
• ISSN: 0008-6223
• DOI: 10.1016/j.carbon.2024.119318

The quest for the materials that boast efficient electromagnetic interference (EMI) shielding, strong strength and superb thermal dimensional stability is a burgeoning research area, particularly due to their critical applications in safeguarding sensitive circuits against microwave radiation, especially in the space environments. Graphene-based composites, leveraging the remarkable attributes of individual graphene nanosheets, emerge as prime contenders for fulfilling these sophisticated application requirements. In this study, we prepared boron-graphene composites via spark sintering, combining graphene sheets and boron nanoparticles. This method not only ensures high-performance outcomes but also remains cost-effective and suitable for large-scale production. Boron serves as a binder, facilitating the connection between adjacent graphene sheets and enhancing the graphitization process. The resulting composites demonstrated exceptional electrical conductivity (4.53 × 105 S m−1) and superior EMI shielding effectiveness (average SET 83 dB, with the thickness of 0.25 mm), markedly surpassing previous graphene-based materials in terms of compressive strength (171.3 MPa), and exhibiting low thermal expansion and an ultra-low friction coefficient (0.04). Additionally, to unravel the evolution of boron in the graphene composite and the impact of boron on electrical conductivity, first principles calculations and density functional theory (DFT) were utilized. This investigation underscores the significant promise of boron-graphene composites as high-performance, multifunctional materials across various domains. [Display omitted] •Boron-graphene composite was high-efficiently fabricated by SPS.•Boron plays a role as binders and promotes the graphitization of graphene.•The resultant composite demonstrates excellent EMI shielding effectiveness.•The resultant composite also shows outstanding multifunctional properties.•Density functional theory elucidates the evolution mechanism of boron in graphene.