Synthesis and characterization of zirconium containing mesoporous silicates and the utilization as support of cobalt catalysts for Fischer–Tropsch synthesis

Using hexadecylpyridinium chloride (C 16PyCl) as cationic surfactant, a series of zirconium containing mesoporous silicates (Zr-MPS) were synthesized at room temperature in a short time. These materials were characterized by powder X-ray diffraction (XRD), N 2 adsorption–desorption, transmission ele...

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Bibliographic Details
Published in:Catalysis communications 2004-10, Vol.5 (10), p.597-603
Main Authors: Wei, Mingdeng, Okabe, Kiyomi, Arakawa, Hironori, Teraoka, Yasutake
Format: Article
Language:English
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Summary:Using hexadecylpyridinium chloride (C 16PyCl) as cationic surfactant, a series of zirconium containing mesoporous silicates (Zr-MPS) were synthesized at room temperature in a short time. These materials were characterized by powder X-ray diffraction (XRD), N 2 adsorption–desorption, transmission electron micrographs (TEM) and XPS. Mesoporous zirconium silicate was used as supports of Co catalysts for Fischer–Tropsch (F–T) synthesis in a slurry phase, and the effect of zirconium in the silicate framework on the catalytic properties and the selectivities for product distribution were investigated.
ISSN:1566-7367
1873-3905
DOI:10.1016/j.catcom.2004.07.014