Supported copper–ceria catalysts for low temperature CO oxidation

In this investigation, CuO/CeO 2–M x O y (M x O y = Al 2O 3, ZrO 2 and SiO 2) nanocomposite oxide catalysts were prepared by deposition-precipitation and wet impregnation methods, and evaluated for CO oxidation. Catalysts were characterized by XRD, TEM, UV–vis DRS, BET surface area and H 2-TPR techn...

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Bibliographic Details
Published in:Catalysis communications 2010-05, Vol.11 (10), p.863-866
Main Authors: Rao, Komateedi N., Bharali, Pankaj, Thrimurthulu, Gode, Reddy, Benjaram M.
Format: Article
Language:English
Subjects:
CO oxidation
CuO/CeO 2
Supported copper oxide catalysts
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Summary:In this investigation, CuO/CeO 2–M x O y (M x O y = Al 2O 3, ZrO 2 and SiO 2) nanocomposite oxide catalysts were prepared by deposition-precipitation and wet impregnation methods, and evaluated for CO oxidation. Catalysts were characterized by XRD, TEM, UV–vis DRS, BET surface area and H 2-TPR techniques. The synthesized catalysts exhibited high specific surface area, and uniform particle size distribution over the supports. The nanocrystalline texture of mixed metal oxides is clearly evidenced by TEM analysis. TPR and XRD results revealed synergetic interactions between copper oxide and ceria. Among various catalysts investigated, the CuO/CeO 2–Al 2O 3 combination exhibited excellent CO oxidation activity with T 1/2 = 374 K and 100% CO conversion at below 420 K.
ISSN:1566-7367
1873-3905
DOI:10.1016/j.catcom.2010.03.009