The effect of textural properties on the hydrogenation of succinic acid using palladium incorporated mesoporous supports

• Published in: Catalysis today 2012-05, Vol.185 (1), p.205-210
• Main Authors: Chung, Sang-Ho, Park, Young-Moo, Kim, Min-Sung, Lee, Kwan-Young
• Format: Article
• Language: English
• Subjects: 1,4-Butanediol; Catalysis; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Heterogeneous Pd catalysts; MCM-41; Porous materials; SBA-15; Succinic acid hydrogenation; Surface physical chemistry; Tetrahydrofuran; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; γ-Butyrolactone
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2011.08.011

[Display omitted] ► Pd/MCM-41 and Pd/SBA-15 were used for the succinic acid hydrogenation. ► The different pore size of the supports affected the size and the location of Pd particles. ► Cyclic chemicals (GBL and THF) were favorably produced with Pd/SBA-15. ► Pd/MCM-41 has larger Pd particles than Pd/SBA-15 and favorably produced BDO. In this study, we examined the effect of the textural properties of support materials on the palladium-catalyzed hydrogenation of succinic acid using mesoporous supports (MCM-41 and SBA-15). The physicochemical properties of these prepared heterogeneous catalysts were characterized by N2 adsorption–desorption, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HR-TEM). When palladium was loaded into the mesoporous supports by incipient wetness method, most palladium particles was incorporated inside the pore channels of SBA-15 support whereas the majority of particles were formed external to the pores of MCM-41 support. The small size of the palladium particles and the large pores of the Pd/SBA-15 catalyst enhanced the catalytic activity on the hydrogenation of succinic acid and the production of γ-butyrolactone (GBL) and tetrahydrofuran (THF); for Pd/MCM-41 catalyst, it was found that the large Pd particles and the small pore size enhanced the production of 1,4-butanediol (BDO). These catalysts showed promise as sustainable alternatives to current methods of manufacture for hydrocarbon derived products such as GBL, THF and BDO.