Nanostructured Co–Ce-O systems for catalytic decomposition of N2O

• Published in: Catalysis today 2012-09, Vol.191 (1), p.121-124
• Main Authors: Dziembaj, Roman, Zaitz, Małgorzata M., Rutkowska, Małgorzata, Molenda, Marcin, Chmielarz, Lucjan
• Format: Article
• Language: English
• Subjects: Catalysis; catalytic activity; CeO2; cerium; Chemistry; cobalt; Cobalt oxide; Colloidal state and disperse state; Decomposition; Emulsions. Microemulsions. Foams; Exact sciences and technology; General and physical chemistry; Microemulsion; Nanomaterials; Nitrous oxide; oxygen; Porous materials; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2012.02.045

[Display omitted] ► A novel, reverse microemulsion method of nanostructured CeO2–Co3O4 oxide systems was developed. ► CeO2–Co3O4 oxide systems were active in catalytic process of N2O decomposition. ► A synergetic effect of dual phase in CeO2–Co3O4 oxide system was observed. Two series of nanostructured materials were obtained by the reverse microemulsion method. It was confirmed obtaining of the nanometric crystallites of Co-substituted ceria solid solutions up to 15mol% of Co, while the reverse oxide system was biphase, even at so low content of CeO2 as 1mol%. The differences in pores structure of the both series were observed as well as the size of crystallites, however limited within nanometric range. The biphase materials showed higher catalytic activity than the solid solutions of Co in ceria phase, though this activity increased with Co content in CeO2 phase.