Vanadium oxide supported on porous clay heterostructure for the partial oxidation of hydrogen sulphide to sulfur

• Published in: Catalysis today 2015-10, Vol.254, p.36-42
• Main Authors: Soriano, M.D., Cecilia, J.A., Natoli, A., Jiménez-Jiménez, J., López Nieto, J.M., Rodríguez-Castellón, E.
• Format: Article
• Language: English
• Subjects: H2S; Porous clay heterostructure; Selective oxidation; V2O5; V4O9
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2014.12.022

•Porous clay heterostructure (PCH) has been synthesized by a sol–gel method.•PCH-xV have shown be active and selective in the partial oxidation of H2S.•Vanadium content is directly related with the catalytic activity.•V4O9 species seem be the active phase in the partial oxidation of H2S. Vanadium oxide supported on porous clay heterostructures (PCH) catalysts have been synthesized, characterized and evaluated in the selective oxidation of H2S to elemental sulfur. The catalysts were characterized by XRD, adsorption–desorption of N2 at −196°C, diffuse reflectance UV–vis, H2-TPR, Raman spectroscopy and XPS. The catalysts with higher vanadium content are more active and selective, exhibiting a H2S conversion close to 70% after 360h on stream with a high selectivity toward elemental sulfur and a low formation of undesired SO2. The catalysts with V2O5 crystallites have shown a higher activity and resistance to the deactivation. The analysis of the spent catalyst has revealed the formation of V4O9 crystals during the catalytic test, which has been reported as the active phase in the selective oxidation of the H2S.