Facile sonochemical synthesis of N,Cl-codoped TiO2: Synthesis effects, mechanism and photocatalytic performance

• Published in: Catalysis today 2015-11, Vol.256, p.365-374
• Main Authors: Teh, Chee Yang, Wu, Ta Yeong, Juan, Joon Ching
• Format: Article
• Language: English
• Subjects: Chlorine; Doping; Dye wastewater treatment; Nitrogen; Photocatalysis; Ultrasound
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2015.02.014

•Codoping nitrogen and chlorine into TiO2 was successful using sonochemical method.•Synthesis using ultrasound was better than mechanical stirring in doping of TiO2.•Formation mechanism of N,Cl-codoped TiO2 using ultrasound was proposed.•Photocatalytic performance of N,Cl-codoped TiO2 was better than P25. In this study, both nitrogen and chlorine were successfully doped into TiO2 (N,Cl-codoped TiO2) via a sonochemical method using titanium(IV) butoxide and ammonium chloride as precursors. When N,Cl-codoped TiO2 was tested on the decolorization of CI Reactive Black 5 (RB5), it was observed that the photocatalytic activity exhibited by the synthesized photocatalyst was greatly affected by the synthesis conditions. Increasing the sonication intensity or duration up to a certain point shifted the absorption onset toward a lower energy and improved the crystallinity of the synthesized photocatalyst. It was also observed that increasing the N,Cl:Ti molar ratio to 2 significantly enhanced the photocatalytic activity of N,Cl-codoped TiO2, but higher molar ratios inhibited the decolorization of RB5. A relatively low calcination temperature of 200°C was sufficient to further improve the photocatalytic activity of N,Cl-codoped TiO2. The following recommended synthesis conditions successfully yielded 96.02% RB5 decolorization under visible light irradiation for 5h: sonication amplitude of 40%, sonication duration of 3.62h, N,Cl:Ti molar ratio of 2 and calcination temperature of 200°C. The decolorization rate constant of N,Cl-codoped TiO2 (0.01min−1) was also significantly higher than that of commercially available P25 (0.0055min−1).