Novel synthesis approaches for WO3‐TiO2/MWCNT composite photocatalysts- problematic issues of photoactivity enhancement factors

• Published in: Catalysis today 2018-02, Vol.300, p.28-38
• Main Authors: Bárdos, Enikő, Kovács, Gábor, Gyulavári, Tamás, Németh, Krisztián, Kecsenovity, Egon, Berki, Péter, Baia, Lucian, Pap, Zsolt, Hernádi, Klára
• Format: Article
• Language: English
• Subjects: Carbon nanotubes; Photocatalysis; Photocatalytic activity; WO3 nanocrystallites; WO3-TiO2 nanocomposites
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2017.03.019

[Display omitted] •The structure and activity is dependent from the synthesis pathway.•The formation of TiWOx was promoted when both precursors were used simultaneously.•The 1st oxide’s calcination is necessary to obtain the 2nd oxide in crystalline form.•Excess of WO3 and MWCNT is detrimental for the photocatalytic activity.•TiWOx and highly crystalline anatase do not coexist in the same composite. The “build-up” methodology, the importance of the order of the semiconductor layers in WO3‐TiO2/MWCNT composite materials was studied in terms of the applied synthesis pathway, morpho-structural parameters (mean crystallite size, crystal phase composition, morphology) and photocatalytic efficiency (using oxalic acid as model pollutant). The appearance of TiWOx phase in the composites contributed to the enhancement of the photocatalytic efficiencies, as different synthesis approaches led to different crystal phase compositions. Although, it was proven that a beneficial phase’s presence can be hindered if an excess of MWCNT or WO3 was applied. As the ratio of the mentioned materials was reduced, active composites were obtained, but the previously noticed TiWOx disappeared. Therefore, it was proven, that in the case of WO3-TiO2/MWCNT nanocomposite system several photocatalytic activity enhancement factors can be introduced, but not simultaneously (the disappearance of TiWOx at low MWCNT and WO3 contents and the appearance of highly crystalline anatase).