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Fabrication of hierarchical bismuth oxyhalides (BiOX, X=Cl, Br, I) materials and application of photocatalytic hydrogen production from water splitting
[Display omitted] •Flower-like hierarchical BiOX (X: Cl, Br, I) microspheres were synthesized using microwave-assisted solvothermal method without template.•Maximum hydrogen evolution rate of 1316.9μmolh−1g−1 was achieved using BiOI at pH 7 under visible light irradiation.•Conduction band level of B...
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Published in: | Catalysis today 2018-06, Vol.307, p.197-204 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | [Display omitted]
•Flower-like hierarchical BiOX (X: Cl, Br, I) microspheres were synthesized using microwave-assisted solvothermal method without template.•Maximum hydrogen evolution rate of 1316.9μmolh−1g−1 was achieved using BiOI at pH 7 under visible light irradiation.•Conduction band level of BiOI catalysts provide a sufficient over-potential to achieve conversion from H+ to H2.
In this article, bismuth oxyhalides (BiOX) have been demonstrated to have remarkable photocatalytic activities due to their uniquely layered strusctures. Hierarchical BiOX (X: Cl, Br, I) microspheres were successfully synthesized by a microwave-assisted solvothermal method from bismuth (III) nitrate pentahydrate (Bi(NO3)3·5H2O) using ethylene glycol and ethanol as solvents. The structures, morphology, and optical properties of the grown BiOX nanostructures were characterized by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), UV–visible diffuse reflectance spectra (DRS), electrochemical impedance spectroscopy (EIS), photoluminescence spectra (PL), and Brunauer-Emmett-Teller (BET) surface area. SEM revealed BiOX to have flower-like structures of microspheres and the as-synthesized photocatalysts were tested for the photocatalytic hydrogen evolution from water splitting via the irradiation of visible light. Among BiOXs as synthesized, BiOI can achieve the maximum hydrogen produciton rate (1316.9μmolh−1g−1) in 360min under visible light irradiation because BiOI not only has a lowest PL intensity than the other BiOX group of materials to better separate the photogenerated electrons and holes, but also a sufficient over-potential of conduction band to achieve the conversion from H+ to H2. |
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ISSN: | 0920-5861 1873-4308 |
DOI: | 10.1016/j.cattod.2017.04.044 |