Modeling TiO2/UV–vis bacterial inactivation: Useful tools for reactor optimization and design

• Published in: Catalysis today 2024-03, Vol.430, p.114520, Article 114520
• Main Authors: Moreno, R., Moles, Samuel, Ormad, Maria P., Mosteo, R., Monzón, A.
• Format: Article
• Language: English
• Subjects: Inactivation; Kinetics; Modeling; Optimization; Photocatalysis; Photorreactor
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2024.114520

Heterogeneous photocatalysis applying TiO2 based catalysts has been widely studied for removing inorganic and organic compounds from water and for bacterial inactivation. This available and low-cost catalyst has demonstrated to be effective in the removal of organic pollutants and inactivation of pathogenic bacteria from water. The design of proper types of industrial-scale photoreactors has not been yet successfully implemented, probably due to the conceptual complexity of modeling this process in real wastewater. As a result, TiO2 based photocatalysis is still considered an effective but energetic-inefficient process. In this work, Escherichia coli (gram-positive) and Enterococcus sp (gram-negative) were selected for studying the kinetics of TiO2 photocatalysis. Since several approaches, such as fist-order kinetics, are not truly representative of the bacterial inactivation process, the experimental data were fitted to different mathematical models, such as Gompertz model, which has demonstrated to describe the process properly. Moreover, the effect of the main variables of the process in the inactivation kinetic constant of the Gompertz model has ben studied. More precisely, light intensity, water matrix, catalyst concentration and bacteria have been under study and their effect has been included in the kinetic equation. Finally, operational and construction parameters of a 20 m3/d annular photoreactor for bacterial inactivation has been successfully optimized applying the proposed kinetic model. [Display omitted] •Gompertz model was applied for modeling photocatalytic bacterial inactivation.•Kinetic constant was defined, incorporating key operational variables influence.•An Analytical model was proposed for annular inactivation photorreactor optimization.