Regiospecific oxidation of an alkyl group of aromatic amine to carbonyl group by DDQ in aq. medium

The regiospecific oxidation of alkyl group of both sterically hindered and unhindered aromatic amine to corresponding carbonyl compound was done in aq. medium by using DDQ. The optimized reaction protocol was found to be most simple, high yielding and novel method for oxidation of alkyl group of aro...

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Bibliographic Details
Published in:Chinese chemical letters 2011-09, Vol.22 (9), p.1039-1042
Main Authors: Mane, Madhav S., Balaskar, Ravi S., Gavade, Sandip N., Pabrekar, Pramod N., Shingare, Murlidhar S., Mane, Dhananjay V.
Format: Article
Language:English
Subjects:
Aq. medium
Aromatic amine
DDQ
Regiospecific oxidation
氧化
烷基
空间位阻
羰基化合物
芳香胺
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Summary:The regiospecific oxidation of alkyl group of both sterically hindered and unhindered aromatic amine to corresponding carbonyl compound was done in aq. medium by using DDQ. The optimized reaction protocol was found to be most simple, high yielding and novel method for oxidation of alkyl group of aromatic amine in to its carbonyl compound.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2011.03.016