Cycloaddition reactions of benzyne with olefins

Some novel cycloaddition reactions based on benzyne and olefins have been developed.These reactions were performed in the absence of a transition metal catalyst,and they displayed good yields.These cycloaddition reactions of benzyne with olefins provide effective routes for synthesizing benzocyclobu...

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Bibliographic Details
Published in:Chinese chemical letters 2014-12, Vol.25 (12), p.1535-1539
Main Authors: Chen, Zhao, Han, Xie, Liang, Jin-Hua, Yin, Jun, Yu, Guang-Ao, Liu, Sheng-Hua
Format: Article
Language:English
Subjects:
9,10-Dihydrophenanthrene
Benzocyclobutenes
Benzyne
Biaryl
Cycloaddition
Olefins
化合物
反应合成
烯烃
环加成反应
苯并环丁烯
苯炔
衍生物
过渡金属催化剂
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Summary:Some novel cycloaddition reactions based on benzyne and olefins have been developed.These reactions were performed in the absence of a transition metal catalyst,and they displayed good yields.These cycloaddition reactions of benzyne with olefins provide effective routes for synthesizing benzocyclobutenes,biaryl compounds and 9,10-dihydrophenanthrene derivatives.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2014.09.013