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The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pu...

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Bibliographic Details
Published in:Chinese chemical letters 2018, Vol.29 (1), p.179-182
Main Authors: Yang, Yifan, Zheng, Qing, Yan, Yuanyuan, Liu, Yao, Shao, Huibo
Format: Article
Language:English
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Summary:This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivariv~ which it ha~pd nn rhp inr~rmnlpcldar hvdrn~en-hnndinct
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2017.06.011