Soft carbon-coated bulk graphite for improved potassium ion storage

• Published in: Chinese chemical letters 2023-03, Vol.34 (3), p.107312, Article 107312
• Main Authors: Chang, Xiaqing, Sun, Ning, Zhou, Huanyu, Soomro, Razium A., Xu, Bin
• Format: Article
• Language: English
• Subjects: Anode materials; Carbon coating; Graphite; Potassium-ion battery; PTCDA
• ISSN: 1001-8417; 1878-5964
• DOI: 10.1016/j.cclet.2022.03.035

Potassium-ion batteries (PIBs) have attracted tremendous attention for large-scale energy storage fields based on abundant potassium resources. Graphite is a promising anode material for PIBs due to its low potassium ion intercalation voltage and mature industrialized preparation technology. However, the inability of graphitic structures to endure large volume change during charge/discharge cycles is a major limitation in their advancement for practical PIBs. Herein, a soft carbon-coated bulk graphite composite is synthesized using PTCDA as a carbon precursor. The PTCDA-derived soft carbon coating layer with large interlayer distance facilities fast potassium ion intercalation/extraction in the BG@C composite and buffers severe volume change during the charge/discharge cycles. When tested as anode for PIBs, the composite realizes enhanced rate capability (131.3 mAh/g at 2 C, 1 C = 279 mA/g) and cycling performance (capacity retention of 76.1% after 150 cycles at 0.5 C). In general, the surface modification route to engineer graphite anode could inherently improve the electrochemical performance without any structural alteration. PTCDA-derived soft carbon was coated on the bulk graphite to promote fast K+ intercalation/extraction in the graphite layer and alleviating large volume changes during the electrochemical reaction, resulting in improved potassium storage performance. [Display omitted]