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Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines
This review covers recent achievements in homogeneous and single-site heterogeneous asymmetric catalysis by metal complexes containing stereohomogeneous ferrocenyl phosphine ligands. The processes reviewed include: reductions of various prochiral substrates, allylic substitutions, hydrosilylations,...
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Published in: | Coordination Chemistry Reviews 2004-12, Vol.248 (21), p.2131-2150 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | This review covers recent achievements in homogeneous and single-site heterogeneous asymmetric catalysis by metal complexes containing stereohomogeneous ferrocenyl phosphine ligands. The processes reviewed include: reductions of various prochiral substrates, allylic substitutions, hydrosilylations, hydroformylations, hydroaminations and hydroborations. Particular attention has been paid to studies aimed at designing novel ligand architectures as well as identifying active catalytic species. |
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ISSN: | 0010-8545 1873-3840 |
DOI: | 10.1016/j.ccr.2004.03.022 |