Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

This review covers recent achievements in the area of low coordinate phosphorus ligands featuring P C double bonds such as phosphaalkenes, phospholide-based complexes and phosphinines. The most significant developments are presented and discussed for each class of ligands. Particular attention has b...

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Bibliographic Details
Published in:Coordination chemistry reviews 2006-03, Vol.250 (5), p.627-681
Main Author: Floch, Pascal Le
Format: Article
Language:English
Subjects:
Phosphaalkene
Phospholide-based complexes
Phosphorus derivatives
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Summary:This review covers recent achievements in the area of low coordinate phosphorus ligands featuring P C double bonds such as phosphaalkenes, phospholide-based complexes and phosphinines. The most significant developments are presented and discussed for each class of ligands. Particular attention has been paid to the use of these new systems as ligands in homogeneous catalysis.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2005.04.032